The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Halogen oxides / Cl oxides / Cl2O3 / JPL-2010(2011)_220-260K_220-320nm(rec)

DATAFILE: Cl2O3_JPL-2010(2011)_220-260K_220-320nm(rec).txt
NAME: dichlorine trioxide, chlorine sesquioxide, chlorine chlorate
FORMULA: Cl2O3
AUTHOR(YEAR): JPL-2010(2011)
T: 220-260K
λ: 220-320nm(rec)
BIBLIOGRAPHY: S.P. Sander, J. Abbatt, J. R. Barker, J. B. Burkholder, R. R. Friedl, D. M. Golden, R. E. Huie, C. E. Kolb, M. J. Kurylo, G. K. Moortgat, V. L. Orkin and P. H. Wine, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 17", JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, 2011; http://jpldataeval.jpl.nasa.gov/
COMMENTS: Structure: ClOClO2

JPL-2010 recommendation, adopting the earlier recommendation of

S.P. Sander, R.R. Friedl, D.M. Golden, M.J. Kurylo, G.K. Moortgat, H. Keller-Rudek, P.H. Wine, A.R. Ravishankara, C.E. Kolb, M.J. Molina, B.J. Finlayson-Pitts, R.E. Huie, V.L. Orkin, “Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 15“, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, 2006; http://jpldataeval.jpl.nasa.gov/ :

220-320 nm, mean of the data of

G.D. Hayman and R. A. Cox, "UV absorption spectrum and thermochemistry of Cl2O3 formed in the photolysis of OClO-containing mixtures at low temperatures," Chem. Phys. Lett. 155, 1-7 (1989); DOI: 10.1016/S0009-2614(89)87350-6 ,

J.B. Burkholder, R.L. Mauldin, III, R.J. Yokelson, S. Solomon, and A.R. Ravishankara, "Kinetic, thermochemical, and spectroscopic study of Cl2O3," J. Phys. Chem. 97, 7597-7605 (1993); DOI: 10.1021/j100131a03,

M.H. Harwood, D.M. Rowley, R.A. Freshwater, R.A. Cox, and R.L. Jones, "A spectroscopic study of Cl2O3," J. Chem. Soc. Faraday Trans. 91, 3027-3032 (1995); DOI: 10.1039/FT9959103027 , and

T.J. Green, M. Islam, P. Guest, K. Hickson, C.E. Canosa-Mas, and R.P. Wayne, "A discharge-flow study of Cl2O3," Phys. Chem. Chem. Phys. 5, 5409-5418 (2003); DOI: 10.1039/B311005B

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